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laboratory skills in macromolecular chemistry: synthesis and characterization of PSU-bioelastomers

1. Synthesis of the Catalyst and Amino-terminated Polysiloxane Macromonomers

  • Synthesis of the tetramethylammonium-3-aminopropyl-dimethylsilanolate catalyst (reported by Hoffman and Leir)
  • Synthesis of α,ω-bis(3-aminopropyl)-polydimethylsiloxanes
  • Synthesis of α,ω-bis(3-aminopropyl)-polydimethyl-methyl-phenylsiloxane

2. Molecular Weight Determination of Polysiloxane

  • Theoretical molecular weight of polysiloxane
  • Molecular weight determination of polysiloxane by 1H-NMR spectroscopy
  • Molecular weight determination of polysiloxane by titration

3. Synthesis of Polysiloxane-urea Elastomers. ATR-FTIR & viscosimetrical Characterization

4. Mechanical Testing

  • Preparation of polysiloxane-urea elastomer films
  • Stress-strain tests on polysiloxane-urea elastomer films
  • Hysteresis tests on PSU elastomer films